The Russian popped six aces, but also committed 11 double faults in the surprise victory. Puchkova broke Williams six times, while the seven-time Grand Slam champion settled for five breaks en route to defeat.
Puchkova’s opponent in Saturday’s final will be Romanian fellow 25-year-old Monica Niculescu, who also advanced via upset on Day 6. Niculescu ousted seventh-seeded 19-year-old Frenchwoman Kristina Mladenovic 6-0, 6-2 in 63 minutes on the hardcourts at Federacao Catarinense de Tenis.
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